Tin - Sn

Chemical properties of tin - Health effects of tin - Environmental effects of tin

Atomic number

50

Atomic mass

118.69 g.mol -1

Electronegativity according to Pauling

1.8

Density

5.77g.cm-3 (alpha) and 7.3 g.cm-3 at 20°C (beta)

Melting point

232 °C

Boiling point

2270 °C

Vanderwaals radius

0.162 nm

Ionic radius

0.112 nm (+2) ; 0.070 nm (+4)

Isotopes

20

Electronic shell

[ Kr ] 4d10 5s25p2

Energy of first ionisation

708.4 kJ.mol -1

Energy of second ionisation

1411.4 kJ.mol -1

Energy of third ionisation

2942.2 kJ.mol -1

Energy of fourth ionisation

3929.3 kJ.mol -1

Discovered by

The ancients

Tin - Sn


Tin

Tin is a soft, pliable, silvery-white metal. Tin is not easily oxidized and resists corrosion because it is protected by an oxide film. Tin resists corrosion from distilled sea and soft tap water, and can be attacked by strong acids, alkalis and acid salts.

Applications

Tin is used in for can coating: tin-plated steel containers are widely used for food preservation. Tin alloys are employed in many ways: as solder for joining pipes or electric circuits, pewter, bell metal, babbit metal and dental amalgams. The niobium-tin alloy is used for superconductiong magnets, tin oxide is used for ceramics and in gas sensors (as it absorbs a gas its electrical conmductivity increases and this can be monitored). Tin foil was once a common wrapping material for foods and drugs, now replaced by the use of aluminium foil.

Tin in the environment

Tin oxide is insoluble and the ore strongly resists weathering, so the amount of tin in soils and natural waters is low. The concentration in soils is generally between the range 1-4 ppm but some soils have less that 0.1 ppm while peats can have as much 300 ppm.
There are few tin-containing minerals, but only one is of commercial significance and that is cassiterite. The main mining area to be found in the tin belt which goes from China through Thailand, Brima and Malaysia to the islands of Indonesia. Malaysia produces 40% of the world's tin. Other important tin mining area are Bolivia and Brazil. Global production is in excess of 140.000 tonnes per year and workable reserves amount to more 4 million tonnes. Tin concetrates are produces in around 130.000 tonnes per year.

Health effects of tin

Tin is mainly applied in various organic substances. The organic tin bonds are the most dangerous forms of tin for humans. Despite the dangers they are applied in a great number of industries, such as the paint industry and the plastic industry, and in agriculture through pesticides. The number of applications of organic tin substances is still increasing, despite the fact that we know the consequences of tin poisoning.
The effects of organic tin substances can vary. They depend upon the kind of substance that is present and the organism that is exposed to it. Triethyltin is the most dangerous organic tin substance for humans. It has relatively short hydrogen bonds. When hydrogen bonds grow longer a tin substance will be less dangerous to human health. Humans can absorb tin bonds through food and breathing and through the skin.
The uptake of tin bonds can cause acute effects as well as long-term effects.

Acute effects are:
- Eye and skin irritations
- Headaches
- Stomachaches
- Sickness and dizziness
- Severe sweating
- Breathlessness
- Urination problems

Long-term effects are:
- Depressions
- Liver damage
- Malfunctioning of immune systems
- Chromosomal damage
- Shortage of red blood cells
- Brain damage (causing anger, sleeping disorders, forgetfulness and headaches)

Effects of tin on the environment

Tins as single atoms or molecules are not very toxic to any kind of organism, the toxic form is the organic form. Organic tin components can maintain in the environment for long periods of time. They are very persistent and not fairly biodegradable. Microrganisms have a great deal of trouble breaking down organic tin compounds that have accumulated on water soils for many years. The concentrations of organic tins still rise due to this.

Organic tins can spread through the water systems when adsorbed on sludge particles. They are known to cause a great deal of harm to aquatic ecosystems, as they are very toxic to fungi, algae and phytoplankton. Phytoplankton is a very important link in the aquatic ecosystem, as it provides other water organisms with oxygen. It is also an important part of the aquatic food chain.

There are many different types of organic tin that can vary greatly in toxicity. Tributyltins are the most toxic tin components to fish and fungi, whereas trifenyltin is much more toxic to phytoplankton.
Organic tins are known to disturb growth, reproduction, enzymatic systems and feeding patterns of aquatic organisms. The exposure mainly takes place in the top layer of the water, as that is where organic tin compounds accumulate.

Sources of periodic table

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