Patents: Ion exchange for water treatment

Water treatment by ion exchange resin

In the treatment of water by the use of a cationic and/or anionic exchange resin, catalyzed hydrazine compound is added to the feed water to alleviate the iron fouling of the ion exchange resin.

Patent number: 4287072

Multi-tank ion exchange water treatment system

A series of ion exchangers are connected in parallel in a water treatment system and are electrically interlocked against simultaneous regeneration. After an exchanger regenerates, it is held in standby status and is automatically returned to service use when another exchanger begins its regeneration cycle.

Patent number: 3932279

Point-of-use water purification system with a cascade ion exchange option

A modular water treatment and purification system, suitable for home use, is connected to a water supply and contains a closed fluid treatment circuit extending to a water outlet. The closed fluid circuit flows through a plurality of replaceable water treatment modules each having a specific water treatment function, such as the removal of a particular material from the water by the use of filtration, carbon adsorption, ion exchange or the addition of a chemical to balance the desired water conditions. Preferably the circuit also includes traversing a radiation device, for example an ultra violet light, for the purpose of sanitizing the water.

Patent number: 6080313

Ion-exchange based fluid treatment systems

A process for removing soluble and insoluble inorganic, organic, and microbiological contaminants from a fluid stream employing a pretreatment module, a post-treatment module, a recharge stream module or any combination thereof, and an ion exchange module, is provided. The process provided reduces the problems associated with ion exchange material fouling and increases contaminant removal capacity.

Patent number: 6878285

Treatment of power plant condensate water with ion exchange resins

A water treatment module and process for treating power plant condensate water utilizing a sulfonated ion exchange resin comprising copolymer beads having an interpenetrating polymer network of at least two polymer components wherein at least one of the polymer components is derived from a monomer mixture having a styrenic content less than about 80 molar percent. In one preferred embodiment the multiple polymer components include: (i) a first polymer component derived from a first monomer mixture comprising a monovinylidene monomer having a styrenic content less than about 50 molar percent and (ii) a second polymer component derived from a second monomer mixture comprising: a second monovinylidene monomer having a styrenic content greater than about 50 molar percent and a crosslinking agent. The ratio of the molar percent crosslinking agent of the first polymer component to the second polymer component is less than about 0.7. The present invention is more effective at removing colloidal iron from condensate water, releases fewer total leachables, releases leachables of a lower molecular weight and/or releases leachable having a reduced sulfonate content

Patent number: 6290854

Method for countercurrent regeneration of an ion exchange resin bed

An improved method for regenerating ion exchange resin in a treatment tank having a flow direction, which includes the steps of providing a supply of regenerant under pressure into the tank, and introducing the regenerant into the tank in an opposite flow direction to the treatment flow direction. In the preferred embodiment, the regenerant is a combination of CO2 which is mixed with water to form carbonic acid and citric acid. This mixture is then introduced into the treatment tank without storage.

Patent number: 6358421

Ion exchange removal of metal ions from wastewater

A novel process and apparatus are disclosed for cleaning wastewater containing metal ions in solution, hydrogen peroxide, and high solids, e.g., greater than about 50 mg/l particulate solids. A carbon adsorption column removes hydrogen peroxide in the wastewater feed containing high solids. A ion exchange unit removes the metal ions from solution. The process and apparatus remove metal ions such as copper from a high solids byproduct polishing slurry from the chemical mechanical polishing (CMP) of integrated circuit microchips to form an environmentally clean wastewater discharge.

Patent number: 6346195

Split ion exchange system and method of operating

An ion exchange system for use in purifying sweetener solutions manufactured in a corn wet milling plant and a method of operating the system. The sweetener solution is passed under pressure through a plurality of ion exchange unit pairs configured to operate in both a parallel and series configuration. This configuration and method of operation has resulted in increased hydraulic capacity, a reduction in system operating pressures, an increased efficiency of impurity adsorption and an increase in the time between regeneration cycles.

Patent number: 6296772

Controllable ion-exchange membranes

Multilayered porous materials are formed by coating a porous substrate with a metal and adsorbing an organic layer comprising a recognition moiety onto the metal film. The recognition moiety interacts with an analyte of interest allowing for its detection, purification, etc. Suitable recognition moieties can be selected from a range of species including, small molecules, polymers and biomolecules and the like. The novel porous materials of the invention can be utilized in an array of methods including, ion-exchange, ion-selective ion-exchange, assays, affinity dialysis, size exclusion dialysis and the like.

Patent number: 6468657

High efficiency ion exchange system for removing arsenic from water

The disclosed invention is a fixed bed ion exchange system from removing arsenic from water. It employs a combination of electronically controlled process steps and specific systems configurations to duplicate the effects of moving resin beds from one operating position to another as is required in moving bed ion exchange water purification systems. The invention combines features of single fixed bed ion exchange systems with those of a moving bed system.

Patent number: 6706195

High efficiency ion exchange system for removing contaminants from water

The disclosed invention is a fixed bed ion exchange water purification system. It employs a combination of electronically controlled process steps and specific systems configurations to duplicate the effects of moving resin beds from one operating position to another as is required in moving bed ion exchange water purification systems. The invention combines features of single fixed bed ion exchange systems with those of a moving bed system. The invention applies to the treatment of water having typical industrial and drinking water concentrations of various ions.

Patent number: 6878286

Method for monitoring advanced separation and/or ion exchange processes

A method of monitoring advanced separation and/or ion exchange processes through the collection of localized data. The data is manipulated to generate preconfigured performance, maintenance, quality assurance, quality control, regulatory, cost reports, performance graphing and historical trends. The data is collected from sensors located at an equipment site and transferred to a remote located by use of the Internet, further all data received and used for generation of reports is also accessible by Internet connection.

Patent number: 6332110

Method and solvent composition for regenerating an ion exchange resin

A method and composition for removing perchlorate from a highly selective ion exchange resin is disclosed. The disclosed approach comprises treating the resin in a solution of super critical or liquid carbon dioxide and one or more quaternary ammonium chloride surfactant compounds.

Patent number: 6407143

High efficiency ion exchange system and method for removing chromium from water

The disclosed invention is a fixed bed ion exchange water purification system. It employs a combination of electronically controlled process steps and specific systems configurations to duplicate the effects of moving resin beds from one operating position to another as is required in moving bed ion exchange water purification systems. The invention combines features of single fixed bed ion exchange systems with those of a moving bed system. The invention applies to the treatment of water having typical industrial and drinking water concentrations of various ions.

Patent number: 7361281

Process for continuous ion exchange

A process for continuous countercurrent ion exchange comprises piping a contaminated feed stream into a closed loop ion exchange contactor. The contactor is an ion exchange bed that has three or more reaction segments. The segments are comprised of at least an adsorption segment for treating the contaminated feed stream, a regeneration segment for stripping the contaminant ions from the resin bed, and a pulse segment for advancing the resin bed. Simultaneously, the feed stream is moved through the contactor in the same direction as the regeneration stream. Measuring the quality of this treated feed stream after it exits the contactor monitors the treatment capacity of the resin bed. In response to this quality measurement, the regenerated resin bed is advanced in the pulse segment of the contactor. The spent brine is recycled back to the contactor until the final effluent brine is highly concentrated. After the resin stops advancing, the feed stream and regeneration stream resume...

Patent number: 7273555