Desalination Post-treatment:

Neutralization / Remineralization for Drinking water


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Why should desalinated water be remineralized?

Reverse Omosis is not a selective ion removal process. After the common 2-pass RO process for Boron Removal, delisalinated water is poor in minerals.

Low mineralized water have few adverse effects:

- High corrosion potential
- Dietary deficiency causing risks of ischaemic heart and cerebrovascular disease (WHO, 2005a; WHO, 2006; Cotruvo, 2006)

The WHO recommends 10 mg/L of Magnesium and 30 mg/L of Calcium for drinking water.

Double-pass SWRO system designed for enhanced Boron removal for dinrking water have a very low mineralization, about 5 to 10 mg/L of Na and 10 to 20 mg/L of Cl. Other ions are below 0.5 mg/L.

Four solutions are widely used to remineralize desalinated water:

 
Remin.
Process
 DescriptionMinerals
1Blend with 1% clarified seawater + pH neutralization15 mg/L Mg + 5 mg/L Ca
+ 125 mg/L Na + 220 mg/L Cl + 25mg/L SO4
pH 7-7.5
2CO2 addition + Calcite Limestone (CaCO3, MgO) percolation + Na2CO380 mg/L CaCO3
pH 7-7.5
3CO2  addition + Dolomite Limestone (CaCO3, MgCO3) percolation + Na2CO380 mg/L CaCO3  + MgCO3
pH 7-7.5
4Addition of CaCl2 + NaHCO3 100 mg/L CaCO3
100 mg/L Na + 50 mg/L Cl
pH 7-7.5

Water Quality for drinking and Irrigation water:

Remin.
Process
TDS after 2-pass SWRO (Boron Removal Process for Drinking Water)EC after SWRO +IX (Boron Removal Process for Irrigation water)SAR after SWRO +IX
(Boron removal Process for Irrigation water)
1350-400 mg/L0.8-0.98
250-100 mg/L0.3-0.42.5
350-100 mg/L0.3-0.42.5
4250-300 mg/L0.6-0.86.5

Processes Comparison:
 
ProcessInvestment OperationWater qualityEase of operation
1Very Low LowMedium water quality - high sodium chloride contentEasy
2HighHigh
 
Good water quality (very small sodium increase)Easy
3HighHigh
 
Very Good water quality (very small sodium increase, more magnesium)Easy
4Very LowLow Medium water quality - high sodium chloride contentTime consuming (chemical dissolution)

 

 

 

 

 

 

Desalination Key issues

Seawater Intake

Desalination Pretreatments

Desalination Post-treatments

Reverse Osmosis Desalination Process

Desalination and Energy Costs

Brine Disposal

Membranes cleaning

Storage and Distribution

Containerization / Tropicalization

Instrumentation and Control (SCADA)

 

 

 

 

 

 

 

 

 

 

 

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